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Emissions of persistent organic pollutants (POPs) TX-2

Dispersion of Toxic Substances Pressure
1 Indicator definition and unit of measurement
Different types of emissions of persistent organic pollutants ( POPs) by economic sector will take place during certain activities. Emissions can be diffuse or originate from known or unknown point sources, and may, consequently be considered as created accidentally or deliberately. This indicator aims at representing all types of emissions of POPs, on a yearly basis (unit: tonnes/year).
2 Placement in the framework
5EAP:
Chapter 4: Selected target sectors, section 4.4 The agriculture sector, table 4: Agriculture and forestry.
Chapter 5: The themes and targets of the programme, section 5.4: Management of water resources, table 11: Water quantity and water quality.
Chapter 6: Management of risks and accidents, section 6.1: Industry-related risks, table 15: Risk management.
Agenda 21:
Chapter 17: Protection of the oceans, all kinds of seas, including enclosed and semi-enclosed seas, and coastal areas and the protection, rational use and development of their living resources.
Chapter 18: Protection of the quality and supply of freshwater resources: application of integrated approaches to the development, management and use of water resources.
Chapter 19: Environmentally-sound management of toxic chemicals, including prevention of illegal international traffic of toxic and dangerous products (section F).
Chapter 20: Environmentally-sound management of hazardous wastes, including prevention of illegal international traffic of hazardous wastes (section D).
International conventions and agreements:
A protocol on atmospheric transboundary transport of persistent organic pollutants is presently being negotiated under the UNECE LRTAP (Geneva, 1979).
Ranking:
Core ranking: 2 (61%)
Policy Relevance: 2 (3.4)
Analytical Soundness: 5 (3.0)
Responsiveness: 1 (3 .0 )
Most appropriate related state indicator:
Accumulated amounts of persistent organic pollutants in parts of society .
3 Significance
Purpose:
The main purpose of this indicator is to represent the total emissions of persistent organic pollutants by economic activity. Different activities lead to different types of emissions. Better knowledge of emitted amounts helps activities aiming at decreasing emissions.
Relevance:
Persistent organic substances are handled by different economic activities, and subsequent emissions of persistent organic pollutants (POPs) take place during production and use, and as waste. Increasing POP emissions, or keeping POP emissions at today’s levelis clearly not sustainable.
Linkages to other pressure indicators:
TX-3: Consumption of toxic chemicals by economic activity; TX-1: Consumption of pesticides by agriculture.
Targets:
None. The 5EAP only sets targets for more environment-friendly agricultural/industrial practices (e.g.: significant reduction of pesticide use per unit of land, chemicals: list of 50 priority chemicals...).
4 Methodological description and underlying definitions
Underlying definitions and concepts:
Persistent organic pollutants are a very large group of different substances. POPs degrade very slowly in the natural environment where they are accumulated and may cause adverse effects. Two groups of chemicals often associated with POPs are halogenated hydrocarbons and polycyclic aromatic hydrocarbons (PAH). Emissions of POPs are probably associated with all economic activities. The total number of POPs is extremely large (several thousand compounds) and the amount is increasing since new substances are frequently synthesised and put into production and use.
Measurement methods:
Information will be generated by emission inventories. A large part of the emissions from products containing POPs will take place not only during production, but also during use and waste treatment. Emitted amounts are estimated by the use of emission factors, describing emission rates of substances from various matrices in different media.
Limitations of the indicator:
The group of persistent organic pollutants is heterogeneous and very large. Their inherent characteristics, their persistence, toxicity and tendency to be accumulated in organisms vary largely, resulting in generalisation difficulties. POPs emitted by society could become metabolised or modified to other new POPs by living organisms in the ecosystem. Today just a small part of all existing POPs is identified and possible to analyse. The emission sources are often diffuse and the emission factors are in some cases unreliable or non-existing.
Alternative definitions:
Emissions of an identified group of persistent organic pollutants or a single persistent organic pollutant by economic activity e.g. emissions of PCBs by economic activity and emissions of anthracene by economic activity.



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