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Index of heavy metal emissions to water TX-4

Dispersion of Toxic Substances Pressure

1 Indicator definition and unit of measurement
Heavy metals are the metals of environmental interest - e.g. mercury, cadmium, lead - with few exceptions - e.g . aluminium. By creating an index, they can be handled in clusters according to sources and emission patterns. Unit: tox. equivalents/yr. 2 Placement in the framework
5EAP:
Chapter 5: The themes and targets of the programme, section 5.2: Acidification and air quality, table 8: Acidification and section 5.4: Management of water resources, table 11: Water quantity and water quality.
Agenda 21:
Chapter 17: Protection of the oceans, all kinds of seas, including enclosed and semi-enclosed seas, and coastal areas and the protection, rational use and development of their living resources.
Chapter 18: Protection of the quality and supply of freshwater resources: application of integrated approaches to the development, management and use of water resources.
Chapter 20: Environmentally-sound management of hazardous wastes, including prevention of illegal international traffic in hazardous wastes (section D).
International conventions and agreements:
Reductions of emissions to waters are agreed upon in OSPARCOM (Oslo, 1972 and Paris, 1974), HELCOM (Helsinki, 1994) and the North Sea Ministerial Conference (Esbjerg Declaration, 1995).
Ranking:
Core ranking: 4 (29%)
Policy Relevance: 3 (3.3)
Analytical Soundness: 3 (3.1)
Responsiveness: 21 (2.4)
Most appropriate related state indicator:
Amounts of heavy metals in water, sediments and sludge.
3 Significance
Purpose:
The main purpose of this indicator is to represent the amounts of heavy metals emitted from different sources and by different processes into water. Better knowledge of emitted amounts helps activities aiming at decreasing emissions.
Relevance:
Metals are totally persistent and all amounts emitted to water will accumulate in water, sediments and, when applicable, sewage plant sludge. Many of the heavy metals are toxic and an accumulation in these media is, consequently, not sustainable.
Linkages to other pressure indicators:
TX-5: Index of heavy metal emissions to air, TX-7: Emissions of heavy metals by consumption.
Targets:
5EAP: 1) Surface water: quality improvement towards a better ecological quality and safeguard of high quality where it exists, 2) Marine water: objectives and actions similar to the North Sea conference (Bonn, 1983) to other sensitive sea areas of the EC.
4 Methodological description and underlying definitions
Underlying definitions and concepts:
Eight heavy metals are in environmental focus: mercury, lead, cadmium, chromium, copper, arsenic, nickel and zinc. The first three are used as indices due to different principle sources and strategies for emission reduction. By focusing on these three, the rest of the heavy metals will roughly be considered.
Measurement methods:
Information will be generated by emission inventories. Traffic, combustion processes will be of large importance. A large part of the emissions from products containing heavy metals will take place not only during production, but also during use and as waste. Emitted amounts are estimated by the use of emission factors, describing emission rates of substances from different matrices and uses.
Limitations of the indicator:
Heavy metals are a heterogeneous group of metals. Their inherent characteristics, such as reactivity and toxic potential, differ. The relationship within the cluster may vary from one location to another and from time to time. The emission sources are often diffuse and the emission factors are in some cases unreliable or non existing.
Alternative definitions:
Emissions of each of the three index-linked metals (mercury, lead, cadmium) are singled out and measured separately, e.g. emissions of cadmium per year.



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